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Synthesis of functionalized macrocyclic derivatives of trioxabicyclo[3.3.0]nonadiene

DOI: 10.3762/bjoc.8.83

Keywords: bisdioxine , macrocyclic amines , macrocyclic nitro compounds , tetraoxaadamantane

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Abstract:

C72-Macrocyclic systems functionalized with nitroaryl and arylamino groups were synthesized from the bisdioxine diacid dichloride 1,3,5,7-tetra-tert-butyl-2,6,9-trioxabicyclo[3.3.1]nona-3,7-diene-4,8-dicarbonyl dichloride (3).

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