Catalytic oxidation of carbazole by t-butyl hydroperoxide over Mo catalysts
过氧化叔丁醇在钼催化剂下对咔唑的催化氧化研究

Catalytic oxidation of carbazole(CAZ) was investigated using oil-soluble t-butyl hydroperoxide(TBHP) as oxidant and Mo(VI) complexes as catalyst.The influences of various factors on CAZ conversion were probed including ligand,supporter and other metals Ni and Co involving.The results show that without supporter molybdenum acetylacetonate(Mo(VI)) has higher activity than MoO3 because of its solubility in hydrocarbon.All supporters,Al2O3,weakly acidic cation exchange resin(D113) and weakly acidic chelating ca...