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Synthesis, structure and ethylene polymerization behavior of titanium complexes [C3H6(N = CH-Ar-O)2]TiCl2
Synthesis, structure and ethylene polymerization behavior of titanium complexes [C3H6(N = CH-Ar-O)2]TiCl2

Keywords: titanium catalyst,titanium complex,tetradentate Schiff,base,ethylene polymerization
乙烯基聚合反应
,钛催化剂,钛合成物,四配位基席夫碱

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Abstract:

Early transition metal catalysts containing twophenoxy-imine ligands, called FI catalysts which havevery high potential to become a new generation of olefinpolymerization catalysts, are new-type catalysts whichhave attracted much attention in recent years1—3]. Many ofthem display activities comparable to those of the metal-locene catalysts and, in some cases, behave as living po-lymerization catalysts of α-olefins. Brookhart and Gibsonet al.4,5] recently reported separately series of Schi…

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