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科学通报(英文版) 2005
Study on anti-pollution nano-preparation of dimethomorph and its performanceKeywords: nano-preparation of pesticide,dimethomorph,photo-,catalysis,TiO2/Ag Abstract: The photocatalysis of nanometer TiO2/Ag was modi- fied by sodium dodecyl sulfate,and its behavior of adsorption for pesticide was investigated on the surface of catalyst.Four kinds of water-olubility preparations were prepared by using TiO2/Ag,modified TiO2/Ag by 0.5% SDS,TiO2 and nothingness as photocatalyst with dimethomorph as effective compo- nent.They were besmeared on a piece of glass,and the photocatalytic experiment was done in sunlight.Degradation rates of 1.2% di- methomorph are 71.5%,68.0%,45.5% and 28.3%,respectively,when it was degraded in five days.Degradation rate of 10% dimetho- morph is 97.3% in eight days in sunlight and t1/2 is 2.8 d in nano-preparation,when it was sprayed on small cabbages after being diluted in rudimental experiments of toxicity for crop.The nano-preparation is of better biologic activity,the virulence of which is 1.235 times as great as original pesticide and 1.245 times as ordinary preparation under the same con- dition.
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