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Coordination polymer based on (1,2-bis(2-picolinamido) phenyl)copper
Coordination polymer based on (1,2-bis(2-picolinamido) phenyl)copper

Keywords: coordination polymer,supramolecular structure,coordination network
聚合物
,(1,2-双(2-甲基吡啶酰胺基)苯基)铜,化学结构,超分子结构,自组合理论

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Abstract:

(1,2-bis(2-pyridinecarboxamido)benzene copper Cu(bpb) was synthesized and employed as a building block to construct supramolecular coordination polymer based on intermolecular coordination and hydrogen bonding interactions. X-ray single-crystal diffraction characterization revealed that intermolecular coordination interactions lead to the formation of one-dimensional infinite molecular columns, which array along the same direction in the crystal resulting in the three-dimensional network. The molecular columns are linked together by hydrogen-bonding interactions, which infinitely extend in bc plane. The one-dimensional coordination bonding and two-dimensional hydrogen-bonding interactions result in the formation of supramolecular coordination polymer.

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