|
金属学报(英文版) 2000
THE CALCULATION OF BaO ACTIVITIES IN BaO-BaF_2-Cr_2O_3 SYSTEM FLUXES USING SCHUHMANN METHODKeywords: Shuhmann method fluxes,activity,Gibbs-Duhem equation Abstract: The principle and steps for the calculation of component activities in fluxes using Schuhmann method are described. On the foris of Gibbs-Duhem equation and using Cr2O3 activities in BaO-BaF2-Cr2O3 system fiuxes, BaO activities at 1523 and 1673K are calculated, respectivelg,and the isoactivity diagrums of BaO are also obtained. The calculation results indicate that BaO activity increases with increasing its content in fiuxes, and decreaaes with the increase of Cr2O3 content at a given XBaO/XBaF2 ratio.
|