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金属学报 2009
OVERALL ACTIVATION ENERGY OF ISOTHERMAL TRANSFORMATION IN METAL ALLOY AND ITS MECHANISM I. Medium Temperature (Bainite) Isothermal Transformation in Steels
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Abstract:
Upper bainite, lower bainite and granular structure in isothermally treated steels have all themselves C curves. A single microstructure is always produced in the primary stage, whereas the nearby two-microstructure complex is usually produced in the medium or final stage of the transformation. Only a single microstructure and Arrhenius equation must be used to deduce the overall activation energy for the transformation product. A combination of overall activation energy, morphology and free energy curve can explain the bainitic transformation mechanism and granular structure formation mechanism. The former follows military atom diffusionless martensite-like shear, which occurred in carbon-depleted region controlled by carbon atom diffusion in austenite, and the latter results from civilian atom diffusionless interface control transformation, which occurred in the most carbon--depleted region controlled by carbon atom diffusion in austenite.