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金属学报  2007 

Electrodeposited Tin based Alloy with Composite Structure Used as Anode Materials for Lithium Ion Batteries
Electrochemical Behavior of Fe—Based Coatings Containing Amorphous Phase Prepared by Electric Arc Spraying

Keywords: lithium-ion battery,copper-tin alloy,pulsed electrodeposition,composite structure anode
Li离子电池
,Cu-Sn合金,脉冲电沉积,复合结构负极,脉冲电沉积,法制,锂离子电池,锡基,合金负极,LITHIUM,ION,BATTERIES,ANODE,MATERIALS,USED,COMPOSITE,STRUCTURE,保持率,循环容量,放电容量,循环性能,合金电极,性能测试结果,电化学,模拟电池,能谱分析,隔离,碳膜

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Abstract:

The porous composite membrane prepared by a phase inversion process was coated on a copper foil,and then tin was electrodeposited on Cu foil through micropore in the composite membrane. The tin-based composites heat-treated under argon atmosphere are used as anode materials for lithium ion batteries.SEM,EDS and electrochemical of the coin cells showed that the electrodeposited tin electrodes with composite structure have the better cycle performance and larger reversible capacity. The first discharge capacity is 538.3 mA.h/g and the charge capacity retention is 85.5% after 50 cyc.

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