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金属学报  2006 

INHIBITION MECHANISM OF STEARAMIDE DERIVATIVE ON THE CORROSION OF CO2
脂肪酰胺类缓蚀剂对X65钢抗CO2腐蚀的机理研究

Keywords: mild steel,corrosion inhibitor,carbon dioxide corrosion,electrochemical polarization,electrochemical impedance spetroscopy (EIS)
低碳钢
,缓蚀剂,CO2腐蚀,电化学极化,电化学阻抗谱

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Abstract:

The mechanisms of the stearamide derivative inhibited CO2 corrosion on the mild steel X65 were studied in derivative containing aerated brine solution by electrochemical polarization measurements and electrochemical impedance spectroscopy (EIS) measurements. The electrochemical data showed that the corrosion resistance was greatly enhanced in the presence of stearamide derivative inhibitor. Polarization curves revealed that the inhibitor is an anodic type inhibitor, belonging to interface adsorbtion, and the inhibition is due to the negative catalytic mechanism. The maximum inhibition efficiency appeared at a concentration of inhibitor of 0.5 g/L. EIS has two time constants and the equivalent circuit was suggested as R(C(R(CR))).

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