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金属学报  1996 

A STUDY ON THE YCl_3-AECl_2(AE=Mg, Ca, Sr, Ba)BINARY PHASE DIAGRAMS
YCl3—AECl2(AE=Mg,Ca,Sr,Ba)二元相图的研究

Keywords: rare earth chloride,phase diagram,thermodynamics,molten salt
稀土氧化物
,相图,热力学,熔盐,,钇合金

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Abstract:

Phase diagram of YCl3-SrCl2 binary system has been measured by means of DTA method, and a new phase in this system was observed by X-ray diffraction. The phase diagrams and thermodynamic properties of the YCl3-AECl2(AE=Mg, Ca, Sr, Ba) systems have been assessed and optimized by using CALPHAD technique. The optimized phase diagrams are consistent with thermodynamical data. (Correspondent: QIAO Zhiyu, professor, Department of Physical Chemistry, University of Science and Technology Beijing, Beijing 100083)

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