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金属学报  1994 

MICROSTRUCTURE AND PROPERTIES OF Au-Cu ALLOYS
Au-Cu合金的微观结构和性质

Keywords: Au-Cu alloy,electronic structure,atomic configuration,heat of formation,lattice constant
Au-Cu合金,电子结构,原子组态,形成热,晶格常数

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Abstract:

According to characteristic crystal theory of alloy phases established on the statistic thermodynamics and electronic theory of metals,a systematic analysis has been conducted on the Au-Cu system. The interaction equations of characteristic properties (energy and volume),electronic structures and their changing characters of characteristic atoms in the Au-Cu alloys have been determined. The theoretical values of heat of formation, mixing Gibbs free energy and lattice constant as a function of concentration are in good agreement with the experimental values.XIE

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