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金属学报 1990
DISSOLUTION BEHAVIOURS OF La IN KCl-NaCl AND LaCl_3-KCo-NaCl MELTS
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Abstract:
The dissolution behaviours of La in KCl-NaCl and LaCl_3-KCl-NaClmelts have been studied by means of the see-through cell, cyclic voltammetry andEHMO of quantum chemistry. The La dissolved in KCl-NaCl melt is found to be ina metallic state, and dissolved in LaCl_3-KCl-NaCl melt ionized into La~(2+) which mayreact furthermore with surrounding La~(3+) to form atom cluster La_m~(n+).