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Molecules  2007 

Comparative Chemical Analysis of the Essential Oil Constituents in the Bark, Heartwood and Fruits of Cryptocarya massoy (Oken) Kosterm. (Lauraceae) from Papua New Guinea

DOI: 10.3390/12020149

Keywords: Cryptocarya massoy, Lauraceae, massoia lactones, 5, 6-dihydro-6-pentyl-2H-pyran-2-one (C-10 massoia lactone), benzyl benzoate, 5, 6-dihydro-6-heptyl-2H-pyran-2-one (C-12 massoia lactones), essential oil analysis, α, β-unsaturated δ-lactone, 5, 6-dihydro-6-nonyl-2H-pyran-2-one (C-14 massoia lactones), δ-decalactone.

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Abstract:

Exhaustive hydro-distillation of the bark, heartwood and fruits of Cryptocarya massoy (Lauraceae) afforded pale yellow-coloured oils in 0.7, 1.2 and 1.0 % yields, respectively. Detailed chemical evaluation of these distillates using GC/MS revealed the major components in the bark and the heartwood oils to be the C-10 (5,6-dihydro-6-pentyl-2H-pyran-2-one) and C-12 (5,6-dihydro-6-heptyl-2H-pyran-2-one) massoia lactones, while the major fruit oil constituent was benzyl benzoate (68.3 %). The heartwood also contained trace amounts of the C-14 (5,6-dihydro-6-nonyl-2H-pyran-2-one) massoia lactone (1.4 %) and the saturated C-10 derivative d-decalactone (2.5 %).

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