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Molecules  2001 

Novel Chiral Switching Ligands for Enantioselective Asymmetric Reductions of Prochiral Ketones

DOI: 10.3390/61200988

Keywords: Oxazaborolidines, dihydrooxazaborins, oxazaaluminium complex, Chiral switch

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Abstract:

The newly developed chiral ligands 1 and 4 show opposite enantioselectivity in the asymmetric reduction of prochiral ketones resulting in the production of either enantiomer depending on the metal complex with high enantiomeric excess.

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