Study on anti-fouling properties and application of PVDF/PMMA and PVDF/TPU blend membranes
PVDF/PMMA与PVDF/TPU共混膜抗污染性能研究及应用

SEM morphologies for novel five-bore PVDF blend modified membranes were observed.The critical fluxes of PVDF/PMMA and PVDF/TPU blend membranes were measured by the flux-step method.The filtration experiments at sub-critical flux and super-critical flux were performed.Then tubular membrane module A(PVDF/PMMA) and B(PVDF/TPU) were used to treat surface water.The results indicated that the PVDF blend modified membranes possessed excellent microstructure and the microstructure of membrane module B was better.The critical fluxes of two membrane modules were 12 L/(m2·h) and 10 L/(m2·h),respectively.The anti-fouling properties of membrane module B were better than those of membrane module A.The operating characteristic under sub-critical flux was more stable than that of super-critical flux.Two membrane modules were used to treat surface water under sub-critical flux and the effects of those with coagulation as pretreatment were studied.The results showed that the wastewater treatment performance of coagulation-ultrafiltration combination process was better than that of ultrafiltration alone process,and the wastewater treatment performance of membrane module B was better than that of membrane module A.