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Molecules  2002 

ElectronTransfer Induced Ring Opening of α-Epoxyketones: Spirodioxolane Formation

DOI: 10.3390/70100063

Keywords: Dioxolanes, Electron transfer, α-Epoxyketones, Photochemistry, Spiro compounds

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Abstract:

Stereospecific formation of spirodioxolanes has been observed on electron transfer induced ring opening of α-epoxyketones by 2,4,6-triphenylpyrylium tetrafluoroborate in the presence of cyclohexanone

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