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环境工程学报 2009
Pyrolytic kinetic analysis of typical components for municipal solid wastes
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Abstract:
Thermogravimetric experiments on typical components of municipal solid wastes were carried out. Based on the experimental data, different forms of reaction mechanism functions were adopted to linear fit calculation, the optimum forms of reaction mechanism functions for the different components were selected, and reaction activation energy(E)and frequency factor(A) were also obtained. Herefrom kinetic model were established to reflect the process of the pyrogenation more accurately. The results indicate that diffuse model is the optimum form for pyrolysis process of majority components.