Synthesis and Structure of the Cadmium (II) Complex: [Cd(C5H5N)2(S2CO-n-C4H9)2]

The [Cd(C5H5N)2(S2CO-n-C4H9)2] adduct of pyridine with [Cd(S2CO-n-C4H9)2]n was synthesized and characterized by IR, elemental analysis,1H-NMR and X-ray diffraction analysis. The crystasl belong to the monoclinic system, space group P2(1)/c with Z=2. Cell dimensions are a=1.1094(12), b=0.6152(6), c=1.7985(19) nm, ？ =96.148(2)°, V=1.2204(2)nm3. The structure was refined to R=0.0246 and wR=0.0645 for 2624 reflections with I>2？(I). The complex has a centrosymmetric molecule structure.