Enhanced and irreversible sorption of pesticide pyrimethanil by soil amended with biochars

Biochar derived from partial combustion of vegetation is ubiquitous and potentially e ective in sequestration of environmental contaminants. Biochars were prepared by burning of red gum (Eucalyptus spp.) woodchips at 450 and 850°C (labeled as BC450 and BC850). These two biochars were found to possess markedly di erent properties in terms of surface area and porosity. Short-term equilibration tests (24 hr) were conducted to assess the sorption-desorption behavior of pyrimethanil in the soil amended with various amounts of biochar of each type, with a special focus on the desorption behavior of the sorbed pesticide through four times successive desorption by dilution. Sorption coe cient and isotherm nonlinearity of the amended soils progressively increased with the content of biochar in the soil. Biochar BC850 with higher surface area and microporosity showed a stronger e ect on the reversibility of sorption pesticide. The soils amended with 5% BC450 and 1% BC850 had nearly the same sorption capacity for pyrimethanil; however, their desorption processes were very di erent with 13.65% and 1.49% of the sorbed pesticide being released, respectively. This study suggested that biochar in soil could be an important factor for immobilization of a pesticide and thus a ecting its environment fate in soil.