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海洋科学  2009 

Study on calculation of phase equilibrium in mixed aqueous electrolyte solutions
混合电解质水溶液相平衡计算的研究

Keywords: electrolyte,phase equilibrium,solid-liquid equilibrium,MINLP,genetic algorithm
电解质
,相平衡,固液平衡,混合整数非线性规划,遗传算法

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Abstract:

A mixed-integer non linear programming(MINLP) model is established for computing phase equilibrium in mixed aqueous electrolyte solutions and a genetic algorithm(GA) is proposed to solve the model.Firstly,based on minimization of Gibbs free energy,the model is established by using a coding method for liquid and crystal salts,and the computation of multiphase equilibrium is transformed into constrained minimization problem.Secondly,the minimization problem is solved by GA,a dynamic coding method that can lim...

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