Electrochemical Degradation of 4-Chlorophenol Using a Pd/MWNTs Catalytic Electrode
用于降解4-氯酚的载钯碳纳米管催化电极研究

Nitric acid in various volume fraction(8%, 15%, 20%, and 68%) was used on the multi-wall carbon nanotubes(MWNTs) pre-treatment and then the formaldehyde reduction method was utilized for the preparation the Pd/MWNTs catalysts which were fully characterized by Boehm titration method, X-ray diffraction(XRD), infrared spectroscopy, scanning electron microscopy(SEM), and cyclic voltammetry(CV) techniques. The electrochemical degradation of 4-chlorophenol was investigated in a diaphragm electrolysis system using the Pd/MWNTs gas-diffusion cathode. The results indicated that the active organic function groups increased on the surface of the carbon nanotube pre-treated by using 68% nitric acid. Pd particles with an average size of 9.2 nm were highly dispersed in the carbon nanotube with an amorphous structure. Additionally, the Pd/MWNTs catalyst in Pd/MWNTs gas-diffusion electrode system accelerated the two-electron reduction of O2 to hydrogen peroxide(H2O2) when feeding air. The Pd/MWNTs gas-diffusion cathode can not only reductively dechlorinate 4-chlorophenols by feeding hydrogen gas, but also accelerate the two-electron reduction of O2 to H2O2 by feeding air. Therefore, the removal efficiency and the average removal efficiency of 4-chlorophenol in terms of total organic carbon(TOC) reached about 86.9% and 71.6% after 140 min electrolysis, respectively.