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环境科学  2012 

Characteristics and Mechanism of 2,4,6-TCP Degradation by the "Fe0/Enriched-Bacteria" System
"Fe0/优势脱氯菌"体系降解2,4,6-TCP特性及机制研究

Keywords: Fe0/enriched-bacteria,2,4,6-trichlorophenol,reductive dechlorination,interface enrichment,degradation pathway
Fe0/优势脱氯菌
,2,4,6-TCP,还原脱氯,界面富集,降解路径

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Abstract:

The synergistic mechanism of 2,4,6-trichlorophenol(TCP) degradation using a combination of Fe0and anaerobic dechlorinating bacteria with batch processing was investigated. Experimental results showed that under the conditions of pH 7.0,Fe0 5 g ·L-1 and 2,4,6-TCP 30mg ·L-1,the growth and interface enrichment of enriched-bacteria could be promoted by Fe0,the cell mass (expressed by D600) of Fe0/enriched-bacteria was about 1.7 times as high as that of the individual predominant groups of dechlorinating bacteria. After 96 h reaction, large amount of bacteria attached to the iron surface, with short rod or coccus-like morphology. The pH value of the system was maintained at 7.8, which could be beneficial to the reductive dechlorination reaction and the growth of the enriched-bacteria. The major pathway of 2,4,6-TCP degradation in the Fe0/enriched-bacteria system was 2,4,6-TCP to 2,4-DCP and then to 4-CP.

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