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环境科学  2008 

Decolorization of the Azo Dye Reactive Red X-3B by an AI-Cu Bimetallic System
Al-CU双金属体系对活性艳红X-3B的脱色研究

Keywords: Al-Cu bimetallic system,reactive red X-3B,decolorization,mechanism,kinetics
Al-Cu双金属体系
,活性艳红X-3B,脱色,机理,动力学

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Abstract:

The decoloration mechanism and kinetics of the azo dye reactive red X-3B by an Al-Cu bimetallic system were investigated by measuring the dye removal, the TOC removal and the aniline concentration, and by adding EDTA as control experiments. The results showed the colority removal rate of X-3B reached 83% in the near neutral pH medium for 30 min and 96.4% for 120 min, in which, about 34% was due to the X-3B reduced to aniline, and about 20% and 30% was due to the flocculating of aluminum ions and surface adsorption of aluminum-fillings respectively. The decolorization of dyeing wastewater is a gradual reaction process, which first adsorbs a large number of dyeing ingredients and then carries out inner electrolysis reduction, improved effectively by the flocculating action of aluminum ions. The decolorization reaction appears to be a pseudo first-order reaction and increases with rising temperature.

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