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环境科学  2009 

Establishment and Application of Gaseous Chlorobenzene UV-Photodegradation Model
紫外光降解反应器去除氯苯气体模型的建立与应用

Keywords: photochemical reaction kinetic,quantum yield,UV photochemical reactor,chlorobenzene,volatile organic compounds(VOCs)
光降解动力学
,量子效率,紫外光化学反应器,氯苯,挥发性有机物

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Abstract:

This work was attempted to provide a model to describe the performance of an UV photochemical reactor to remove gaseous chlorobenzene. Based on photochemical process and linear source sphere emission(LSSE) irradiation energy distribution, the model established in this study indicated that the performance of the reactor was dependent on the local volumetric rate of energy absorption (LVREA) inside reactor, the empty bed residence time and the inlet concentration. Moreover, the model was used to predict the outlet concentrations under the operating conditions of various inlet chlorobenzene concentrations and empty bed residence time. Finally, the model shows theory significance for the engineering design and operation of the UV photochemical reactor.

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