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环境科学  2007 

Nano-MnOx Catalyst for the Selective Catalytic Reduction of NO by NH3 in Low-temperature
低温条件下Nano-MnOx上NH3选择性催化还原NO

Keywords: selective catalytic reduction (SCR),low-temperature,NO,ammonia,MnOx
选择性催化还原
,低温,一氧化氮,,锰氧化物

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Abstract:

Nanometer particles composed of manganese oxides (Nano-MnO(x)), which prepared by rheological phase reaction method, show superior low-temperature SCR activity for NO with NH3 in the presence of excess O2. In experiments, the NO conversion is 98.25% at 80 degrees C, and nearly 100% NO could be converted in 100 - 150 degrees C. Due to the reason of competing adsorption, H2O has a slight impact on the activity and the deactivation of SO2 is reversible. The experiments implied that the superior low-temperature catalytic activity of Nano-MnO(x) was mainly due to its high BET specific areas and poor crystallinity.

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