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环境科学  1999 

Photocatalytic Degradation of Pesticide Imidacloprid Using Adherent TiO2 Catalysts
附载TiO2光催化降解咪蚜胺农药

Keywords: TiO2
光催化
,咪蚜胺,降解机理,降解速率,降解动力学

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Abstract:

TiO2 catalysts adhered to the glass were used for investigating photocatalytic degradation of pesticide imidacloprid in aqueous solution under 3×8W fluorescent lamps.The results showed that the photocatalytic degradation rate of imidacloprid was high and up to above 50%.And the photolysis fit a first-order kinetic relationship well.The photolysis rate constant of imidacloprid decreased with increasing initial concentration,which was explained by two mechanisms of photocatalytic degradation.By contrast,adherent TiO2 films with adding Carboxymethyl Cellulose-Na to treat was not easy to take off and the catalytic activity would not drop.In addition,the feasibility the imidacloprid photocatalytic degradation under the sunlight was also studied.

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