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高分子学报 2009
PREPARATION OF SOLUBLE POLYIMIDE AND ITS POTENTIAL APPLICATION IN LIQUID CRYSTAL DISPLAYS
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Abstract:
The diamine monomers 4,4'-diamino-3,3'-dimethyldiphenylmethane(DMMDA)and 4-diphenyl 3,5-diaminobenzoate(DABBE)were successfully synthesized.Polyimides containing asymmetric units in the main chain and biphenyl pendant groups were synthesized with the copolymerization of DMMDA,DABBE and aromatic dianhydride 4,4'-oxydiphthalic anhydride(ODPA)by chemical imidization.The structures and properties of the resulting co-condensation type polyimides were characterized by IR,GPC,UV-Vis and DSC etc.The polyimides as a...