RADICAL POLYMERIZATION OF DIALKYL FUMARATES
反丁烯二酸酯类的自由基聚合反应研究

Radical polymerization of 14 kinds of different dialkyl fumarates (DRFs) in the presence of AIBN and BPO were studied. It has been found that all DRFs monomers can undergo ho- mopolymerization in the presence of free radical initiators. The polymerization reactivities of DRFs increase in the following order: DCHF>DtBF>DiPF>MiPF, DEF, DsBF, DsAF> DEHF>DnHF>DiBF, DiAF, DnPF, DnBF, DnAF. This phenomenon was explained on the basis of analysis of DRFs monomers structures. Structures of DRFs polymers as well as their properties were characterized by means of IR, 1H-NMR etc..