GROUP TRANSFER BLOCK COPOLYMERIZATION BY BIFUNCTIONAL INITIATORS
用双官能团引发剂进行的基团转移嵌段共聚研究

It was reported the group transfer block copolymerization of methacrylates and arylates with bifunctional initiators and bibenzoate catalyst. ABA-triblock copolymers of MMA and BA, MMA and BMA, MMA and EMA with predetermined molecular weight and low poly-dispersity were obtained. The copolymers were characterized by 1H-NMR, GPC and DSC. The effects of the block sequence, catalyst concentration, solvent polarity on block copolymerization were studied.