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高分子学报 2009
PREPARATION OF PNIPAAm GRAFTED COTTON AND ITS THERMAL SENSITIVITY
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Abstract:
The thermal sensitive cotton-g-PNIPAAm was prepared through free radical grafting reaction initiated by different initiators including ammonium ceric nitrate(CAN),potassium persulfate(KPS) and hydrogen peroxide/ascorbic acid(H_2O_2/H_2A system).The degrees of grafting(G) achieved by different initiators could be sorted into descent order as following: G(H_2O_2/H_2A)>G(KPS)>G(CAN).The other factors affecting the degree of grafting,such as the concentration of initiator,reaction time,temperature and the conce...