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高分子学报 1982
COHESION ENERGY DENSITY AND GLASS TRANSITION TEMPERATURE OF 1,2-POLYBUTADIENES
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Abstract:
Cohesion energy density of 1,2-polybutadienes with various content of 1,2-unit was obtained from solubility parameter which was measured in mixed solvents of cyclohe-xane and toluene.It was found that with increasing in the content of 1,2-unit of the polymer, its glass transition temperature increases but the cohesion energy density decreases, due to the stiffening of the molecular chains of 1,2-polybutadienes.