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高分子学报 2009
NUCLEATION PROCESS AND NUCLEATION MECHANISM OF MMA/BA SEEDED SEMI-CONTINUOUS EMULSION POLYMERIZATION
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Abstract:
A water-insoluble dye(BL-S)was used as a probe to study the influence of some factors on the process of nucleation and nucleation mechanism in seeded semi-continuous emulsion polymerization.Some parameters were analysed for quantitative study on nucleation mechanisms,the parameters include the amount of dye incorporated into the resultant latex particles(P_dye),number of the resultant latex particles(Nc_p)and the different numbers of particles which are formed by micellar nucleation(N_m)and homogeneous nucl...