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高分子学报 1989
STUDY ON THE PREPARATION AND PORE STRUCTURES OF COPOLYMER OF TRIALLYL CYANURATE AND METHYL ACRYLATE
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Abstract:
Copolymer is prepared by the suspension copolymerization of triallyl cyanurate (TAC) and methyl acrylate (MA) in the presence of diluents such as cyclohexane, n-butyl ether, or toluene-gasoline (200#). The pore-structure parameters of the copolymer beads were determined. The study of pore structure shows that average pore radius is 10000-80000 A. The effects of molecular structure and amounts of the diluents on the pore structure of the beads were studied. The mechanism of forming super-macropore was disscued preliminarily.