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高分子学报 1982
CRYSTALLIZATION AND MORPHOLOGY OF HIGH CIS 1,4-POLYBUTADIENE
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Abstract:
Cis 1,4-polybutadiene synthesized by rare-earth catalyst has high cis content, high degree of molecular reqularity and low degree of branching. The crystallization and morphology of the polymer were studied at low temperature with electron microscope-It was observed that the morphology and growth rate of spherulites are affected by the degree of molecular regularith and conditions of crystallization.