STUDIES ON POLYMERIZATION KINETICS OF METHYL METHACRYLATE AT HIGH CONVERSION
甲基丙烯酸甲酯高转化聚合动力学的研究

The bulk polymerization of methyl methacrylate which were carried out in a metallic dilatometer and DSC have been studied over the complete course of the reaction. An attempt was made to quantitatively express the relation on the onset of gel effect and the final conversion with polymerization conditions such as temperature, kinds and concentration of initiators. It was demonstrated further that the final conversion of polymerization in homogeneous ideal systems is only dependent on reaction temperature.