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高分子学报 1985
KINETICS OF PROPYLENE POLYMERIZATION ON COMPLEX-CATALYSTS
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Abstract:
We presented the results of propylene polymerization-kinetics on complex-catalysts obtained from reduced TiCl4, by complexation of AlEt2Cl and. isoamyl ether. The characteristics of reacting kinetic curves of polymerization were measured in the normal pressure. The rate constant, reaction order 'and activation energy were measured and rate equation, r=KGP, was developed. Experimental data of the stereoregularity of polymer was discussed in the light of the kinetic behavior of the catalyst System.
