Preparation of Proton Conductive Electrolyte from Poly(vinylidene fluoride-co-hexafluoropropylene) by Grafting Poly(sulfopropyl methacrylate)
聚偏氟乙烯-六氟丙烯接枝聚丙烯酸磺酸丙酯制备质子膜

Poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) grafted poly(sulfopropyl methacrylate) (PSPMA) (PVDF-HFP-g-PSPMA) copolymer as proton conductive electrolyte by atom transfer radical polymerization of sulfopropyl methacrylate (SPMA) at the secondary halogenated sites of PVDF-HFP was prepared and characterized. The structure of PVDF-HFP-g-PSPMA copolymer was verified by FT-IR spectroscopy and proton nuclear magnetic resonance spectrometry. The PVDF-HFP-g-PSPMA membrane showed the ion exchange chro...