|
过程工程学报 2006
Preparation of Isolated Single-walled Carbon Nanotubes with High Hydrogen Storage CapacityKeywords: carbon nanotubes,synthesis,alcohol,benzene,mechanism Abstract: Isolated single-walled carbon nanotubes with high proportion of opening tips were synthesized by using alcohol as carbon source. The mechanism of cutting action of oxygen was proposed to explain its growth. Compared with carbon nanotubes synthesized with benzene as carbon source, their specific surface area was heightened by approximately 2.2 times (from 200.5 to 648 m2/g) and the hydrogen storage capacity was increased by approximately 6.5 times (from 0.95 to 7.17%, ω)which had exceeded DOE energy standard of vehicular hydrogen storage.
|