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过程工程学报 2002
Co-liquefaction of Enriched Coal Maceral Constituents and SawdustKeywords: co-liquefaction,coal,vitrinite,fusinite,sawdust Abstract: Co-liquefaction of coal and sawdust was studied in the presence of hydrogen-donor solvent, tetralin. Coal samples were prepared through floatation of the Xinwen coal, followed by enrichment of maceral constituents. Sample I was rich in vitrinite and Sample II fusinite. Effects of reactiontemperature, time and initial cold H2 pressure were studied on conversion, yield, especially oil yield,through comparison between these two samples. Because it is more difficult to be liquefied, Sample II, is greatly affected by changes in temperature and time. However, it is almost independent of change ininitial cold H2 pressure, owing to the role of tetralin as hydrogen vehicle. Certain product(s) formed from thermolysis of sawdust can help hydrogenation of the intermediate (asphaltene and preasphaltene) infurther forming oil products.
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