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光子学报 2008
Quantum Analysis of Methanol Fluorescent Spectra
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Abstract:
The fluorescent spectra of methanol was studied.Methanol was regarded as diatomic molecule approximatively,methyl and hydroxy were regarded as atomic massion respectively in experiment.The difference of electronic energy level of diatomic molecule was estimated by the means of numerical calculation,and then it was denoted in a function just related to molecular size.The bond length of C-O qua the molecular size was substituted into anterior function to calculate the central difference of transition energy level.Comparing the result with experimental value,the error is 2.2%,it indicates that the theory and the experiment inosculate very well.