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腐蚀科学与防护技术 2004
SEMI - CONDUCTIVE BEHAVIOR DURING DEGRADATION OF A RUST PREVENTIVE OIL FILM ON 304 STAINLESS STEEL IN 3% NaCl SOLUTION
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Abstract:
In this paper,conducting transformation of a rust preventive oil film on 304 stainless steel in 3% NaCl solution under potential was studied by means of potential-capacitance method and Mott-Schottky analysis.It was pointed out that there existed semiconducting behaviour of the rust preventive oil film during its degradation.With increasing immersion time the rust preventive oil film transformed from p type semiconductor at the early stage of immersion to n type semiconductor,two transition layers of space charge gradually formed in the rust preventive oil film.N D and N A of oil film in different transition process were also calculated.