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腐蚀科学与防护技术 2009
STUDY ON CORROSION OF MAGNESIUM ALLOY IN SIMULATED COOLING WATER BY MEANS OF IN SITU SPECTROSCOPIC ELLIPSOMETRY
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Abstract:
In situ spectroscopic ellipsometry was employed to investigate the corrosion behavior of AZ40 magnesium alloy in a simulated cooling water without and with molybdate inhibitor.By deconvoluting the ellipsometric data with a one-layer model,the evolution of the refractive indices and the thickness of the interface layer of "electrode-medium" were obtained.Based on the deconvolution results,three regimes,which were dissolution of native oxide film,formation of adsorption film and precipitation of corrosion pro...