THE PREPERATIONS,ELECTRIC AND MAGNETIC PROPERTIES,AND CHARGE TRANSFER PROPERTIES OF M(C_3S_5)_2 TYPE OF MOLECULAR CONDUCTORS
M（C3S5）2型分子导体的制备及其电磁和电荷转移性质

Crystalline molecular conductors Ni(C3S3)2. Pd(C3S3)2 and Pt(C3S3)2 have been prepared and the material synthesizing conditions have been discussed. The resistance-temperature curves and the magnetic susceptibility-temperature curves have been determined. Based on molucular and crystal orbital calculations and spectroscopic analyses, the energy band structure of Ni(C3S3)2 has been propoesd. The charge transfer between IM(C3S3)2]-and M(C353)2;between M(C3S3)2]2- and IM(C3S3)2]-; and between M(C3S3)2]2-and M(C3S3)2 have also been studied.