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材料科学技术学报 1989
A Study on Synthesis Kinetics of YBa_2Cu_3O_x High Tc Superconductor PowderKeywords: High T_c superconductor,synthesis kinetics,calcination process,sintering of multiphase powder Abstract: The synthesis kinetics of YBa_2Cu_30_x supercon-ductor was studied through comparing the calcina-tion (sintering) processes of different kindsof powders. It was shown that the temperatureof synthesis of YBa_2Cu_30_x phase can be loweredfrom 950℃ to 800℃ through direct calcinationof multiphase powder with uniform chemical com-position. The stress which is caused by thevolume change during synthetic reaction breaksthe particles. It facilitates the formationof highly active superfines of superconductor.
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