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Hyperspherical Calculations on Electron Affinity and Geometry for Li- and Na-
Hyperspherical Calculations on Electron Affinity and Geometry for Li^- and Na^-

Keywords: 31,15,Ja,32,10,Hq,36,40,Mr
超球面计算
,电子亲和力,锂离子,钠离子

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Abstract:

Using a model potential to describe the interaction between the core and the valence electron, we perform hyperspherical calculations for electron affinity and geometry of the weakly bound Li^- and Na^- systems. In our calculation, channel functions are expanded in terms of B-splines. Using the special properties of B-splines, we make the knot distributions more precisely, characterizing the behaviour of channel functions. This improves the convergence greatly. Our results are in good agreement with the other theoretical and experimental values.

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