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中国物理快报 2009
Luminescent Characteristics of LiSrBO3:Eu3+ Phosphor for White Light Emitting Diode
Keywords: 78,55,-m,33,50,Dq,33,20,Kf Abstract: LiSrBO3:Eu3+ phosphor is synthesized by a high solid-state reaction method, and its luminescent characteristics are investigated. The emission and excitation spectra of LiSrBO3:Eu3+ phosphors exhibit that the phosphors can be effectively excited by near ultraviolet (401nm) and blue (471nm) light, and emit 615nm red light. The effect of Eu3+ concentration on the emission spectrum of LiSrBO3:Eu3+ phosphor is studied; the results show that the emission intensity increases with increasing Eu3+ concentration, and then decreases because of concentration quenching. It reaches the maximum at 3mol%, and the concentration self-quenching mechanism is the dipole-dipole interaction according to the Dexter theory. Under the conditions of charge compensation Li+, Na+ or K+ incorporated in LiSrBO3, the luminescent intensities of LiSrBO3:Eu3+ phosphor are enhanced.
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