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力学学报  1995 

EFFECTS OF ANHARMONICITY AND MASS FACTOR ON MOLECULAR VIBRATIONAL RELAXATION OF DIATOMICS IN CONDENSED STATE
稠密流体中双原子分子振动弛豫的非谐性及质量效应

Keywords: molecular dynamics,condensed state,nonharmonic effect,mass factor
分子动力学
,稠密态,非谐性效应,质量因子

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Abstract:

In this note,we investigate the effects of anharmonicity and mass for diatomicmolecular vibrational relaxation in condensed fluid by computer simulation. We have shownthat the rates of vibrational relaxation increase with the increase of anharmonicity and massfactor. This is in agreement with the data from experiment.

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