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Crystals  2012 

Theoretical Studies on Phase Transitions in Quasi-One-Dimensional Molecular Conductors

DOI: 10.3390/cryst2030996

Keywords: molecular conductors, quasi-one-dimension, phase transition, charge order, metal-insulator transition, symmetry breaking, bosonization, renormalization group, quantum Monte Carlo, extended Hubbard model

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Abstract:

A review is given for recent theoretical studies on phase transitions in quasi-one-dimensional molecular conductors with a quarter-filled band. By lowering temperature, charge transfer salts exhibit a variety of transitions accompanying symmetry breaking, such as charge ordering, lattice dimerization, antiferromagnetic transition, spin-Peierls distortion, and so on. Analyses on microscopic quasi-one-dimensional models provide their systematic understandings, by the complementary use of different analytical and numerical techniques; they can reproduce finite-temperature phase transitions, whose results can be directly compared with experiments and give feedbacks to material design.

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