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岩石学报  2001 

The dynamical model of chemical oscillation in CaF2-HCl-H2O solid-liquid reaction system.
固—液反应体系CaF2—HCl—H2O内化学振荡的动力学模型

Keywords: Solid-liquid reaction system,Chemical oscillation,Dynamical model,Hopf branch
固-液反应体系
,化学振荡,动力学模型,Hopf分叉,氟化钙-氯化氢-水,物理化学

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Abstract:

This study is based on the physical chemistry elementary principle to propose that the surface adsorptioncatalytic mechanism of HF is the key to dissolving oscillation of CaF2-HCl-H2O solid-liquid reaction system. Meanwhile a dynamical model of this system is proposed in order to study its non-linear dynamical genesis. Although this mathematical model is based on CSTR reaction apparatus, it is applicable to the foliate flow reaction apparatus also.

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