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岩石学报 2001
The dynamical model of chemical oscillation in CaF2-HCl-H2O solid-liquid reaction system.
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Abstract:
This study is based on the physical chemistry elementary principle to propose that the surface adsorptioncatalytic mechanism of HF is the key to dissolving oscillation of CaF2-HCl-H2O solid-liquid reaction system. Meanwhile a dynamical model of this system is proposed in order to study its non-linear dynamical genesis. Although this mathematical model is based on CSTR reaction apparatus, it is applicable to the foliate flow reaction apparatus also.