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物理学报  2012 

The degradation mechanisms of lamp used BaMgAl10O17: Eu2+,Mn2+ phosphor
节能灯用BaMgAl10O17:Eu2+,Mn2+荧光粉的劣化机理研究

Keywords: BaMgAl10O17Eu2+,Mn2+,thermal degradation,ultraviolet radiation degradation
BaMgAl10O17Eu2+
,Mn2+,热劣化,紫外辐照劣化

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Abstract:

The thermal and the ultraviolet radiation degradation mechanisms of lamp used BaMgAl10O17:Eu2+, Mn2+ phosphor are investigated in a comparative way. Thermal and the ultraviolet radiation treatments can both seriously damage the luminous efficiency of BaMgAl10O17:Eu2+,Mn2+. It is revealed that the thermal degradation is involved in the oxidation and migration of Eu2+ ions. The ultraviolet radiation makes the Eu2+ in metastable state, which weakens the direct absorption of Eu2+ and thus reduces the relative luminescence intensity of BaMgAl10O17:Eu2+,Mn2+.

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